CHARGE COMPONENTS OF INDUCTIVE EFFECT OF ALKYL GROUPS AND THEIR INFLUENCE ON THE CHEMOSELECTIVITY OF ALCOHOLS BENZOYLATION

Author(s)

CHARGE COMPONENTS OF INDUCTIVE EFFECT OF ALKYL GROUPS AND THEIR INFLUENCE ON THE CHEMOSELECTIVITY OF ALCOHOLS BENZOYLATION Kima Petrosyan

The inductive effect of alkyl groups of alcohols is an additive quality, which arises because of the differences in electronegativities of atoms of hydrogen, carbon, and oxygen in the molecule of alcohol are provided. Thanks to that a negative charge is formed on carbon atoms of the C–H bond, and a positive charge on carbon atoms of C–O bond. We show that these charges are equivalent to the natural forces of affinity, which cause the chemoselectivity of molecules.

DOI: 10.46991/PYSUB.2016.50.3.019 Chemical and Biological Sciences 50 (3 (241) 19-24

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Keywords

electronegativity, chemoselectivity of molecules, acid of Pauling, base of Pauling

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